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Extra info for Advances in Dendritic Macromolecules : 1995 (Advances in Dendritic Macromolecules) (Advances in Dendritic Macromolecules)

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1994,26,187. 43. Wooley, K. ; Hawker, C. ; Pochan, J. ; Fr6chet, J. M. J. Macromolecules 1993, 26,1514. 44. ; White, J. W; Hawker, C. J,; Wooley, K. ; Fr6chet, J. M. J. 7. Phys. Chem. 1993,97, 293. This Page Intentionally Left Blank CASCADE MOLECULES: BUILDING BLOCKS, MULTIPLE FUNCTIONALIZATION, COMPLEXING UNITS, PHOTOSWITCHING Rolf Moors and Fritz VogtIe ABSTRACT I. INTRODUCTION A. Repetitive Synthesis II. TOSYLAMIDE CASCADES A. Divergent Synthetic Strategy B. Convergent Synthetic Strategy III.

This raises the unique question as to the types of three-dimensional architectures that may be considered block copolymers. , 16 and 17), dendritic segment-block, and dendritic layer-block copolymers. The three different architectures are represented schematically in Figure 6. As their name implies, dendritic segmentblock copolymers are characterized by different segments or fragments emanating radially from a central core, while dendritic layer-block copolymers have concentric layers of different chemistry around the central core.

Wooley, K. ; Hawker, C. ; Frechet, J. M. J. Polym. Prep. 1991, 32, 631. 36. Gitsov, L; Wooley, K. ; Frechet, J. M. J. Angew. Chem. Int. Ed Engl. 1992, 31, 1200. 37. Gitsov, L; Wooley, K. ; Hawker, C. ; Ivanova, P T; Frdchet, J. M. J. Macrvmolecules 1993,26,5621. 38. Gitsov, L; Frechet, J. M. J. Unpublished results. 39. Mourey, T. ; Turner, S. ; Frechet, J. M. ; Hawker, C. ; Wooley, K. L. Macromolecules 1992,25, 2401. The Convergent-Growth Approach 39 40. Lescanec, R. ; Muthukumar, M. Macromolecules 1990, 25, 2280.

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